4.5 The Carnot Cycle

In the early 1820s, Sadi Carnot (1786−1832), a French engineer, became interested in improving the efficiencies of practical heat engines. In 1824, his studies led him to propose a hypothetical working cycle with the highest possible efficiency between the same two reservoirs, known now as the Carnot cycle. An engine operating in this cycle is called a Carnot engine. The Carnot cycle is of special importance for a variety of reasons. At a practical level, this cycle represents a reversible model for the steam power plant and the refrigerator or heat pump. Yet, it is also very important theoretically, for it plays a major role in the development of another important statement of the second law of thermodynamics. Finally, because only two reservoirs are involved in its operation, it can be used along with the second law of thermodynamics to define an absolute temperature scale that is truly independent of any substance used for temperature measurement.

With an ideal gas as the working substance, the steps of the Carnot cycle, as represented by Figure 4.11, are as follows.

1. Isothermal expansion. The gas is placed in thermal contact with a heat reservoir at a temperature $T_{\text{h}}.$ The gas absorbs heat $Q_{\text{h}}$ from the heat reservoir and is allowed to expand isothermally, doing work $W_1.$ Because the internal energy $E_{\text{int}}$ of an ideal gas is a function of the temperature only, the change of the internal energy is zero, that is, $\text{Δ}{E}_{\text{int}}=0$ during this isothermal expansion. With the first law of thermodynamics, $\text{Δ}{E}_{\text{int}}=Q-W,$ we find that the heat absorbed by the gas is
   $$Q_{\text{h}}=W_1=nR{T}_{\text{h}}\text{ln}\frac{V_N}{V_M}.$$

   Figure 4.11 The four processes of the Carnot cycle. The working substance is assumed to be an ideal gas whose thermodynamic path MNOP is represented in Figure 4.12.

   Figure 4.12 The total work done by the gas in the Carnot cycle is shown and given by the area enclosed by the loop MNOPM.
2. Adiabatic expansion. The gas is thermally isolated and allowed to expand further, doing work $W_2.$ Because this expansion is adiabatic, the temperature of the gas falls—in this case, from $T_{\text{h}}\text{to}{T}_{\text{c}}.$ From $p{V}^{\gamma }=\text{constant}$ and the equation of state for an ideal gas, $pV=nRT$, we have
   $$T{V}^{\text{γ}\text{−}\text{1}}=\text{constant},$$
   so that
   $$T_{\text{h}}{V}_N{}^{\gamma -1}=T_{\text{c}}{V}_O{}^{\gamma -1}.$$
3. Isothermal compression. The gas is placed in thermal contact with a cold reservoir at temperature $T_{\text{c}}$ and compressed isothermally. During this process, work $W_3$ is done on the gas and it gives up heat $Q_{\text{c}}$ to the cold reservoir. The reasoning used in step 1 now yields
   $$Q_{\text{c}}=nR{T}_{\text{c}}\text{ln}\frac{V_O}{V_P},$$
   where $Q_{\text{c}}$ is the heat dumped to the cold reservoir by the gas.
4. Adiabatic compression. The gas is thermally isolated and returned to its initial state by compression. In this process, work $W_4$ is done on the gas. Because the compression is adiabatic, the temperature of the gas rises—from $T_{\text{c}}\text{to}{T}_{\text{h}}$ in this particular case. The reasoning of step 2 now gives
   $$T_{\text{c}}{V}_P{}^{\gamma -1}=T_{\text{h}}{V}_M{}^{\gamma -1}.$$
   The total work done by the gas in the Carnot cycle is given by
   $$W=W_1+W_2-W_3-W_4.$$

This work is equal to the area enclosed by the loop shown in the pV diagram of Figure 4.12. Because the initial and final states of the system are the same, the change of the internal energy of the gas in the cycle must be zero, that is, $\text{Δ}{E}_{\text{int}}=0$. The first law of thermodynamics then gives

and

To find the efficiency of this engine, we first divide $Q_{\text{c}}\text{by}{Q}_{\text{h}}:$

When the adiabatic constant from step 2 is divided by that of step 4, we find

Substituting this into the equation for $Q_{\text{c}}\text{/}{Q}_{\text{h}},$ we obtain

Finally, with Equation 4.2, we find that the efficiency of this ideal gas Carnot engine is given by

An engine does not necessarily have to follow a Carnot engine cycle. All engines, however, have the same net effect, namely the absorption of heat from a hot reservoir, the production of work, and the discarding of heat to a cold reservoir. This leads us to ask: Do all reversible cycles operating between the same two reservoirs have the same efficiency? The answer to this question comes from the second law of thermodynamics discussed earlier: All reversible engine cycles produce exactly the same efficiency. Also, as you might expect, all real engines operating between two reservoirs are less efficient than reversible engines operating between the same two reservoirs. This too is a consequence of the second law of thermodynamics shown earlier.

The cycle of an ideal gas Carnot refrigerator is represented by the pV diagram of Figure 4.13. It is a Carnot engine operating in reverse. The refrigerator extracts heat $Q_{\text{c}}$ from a cold-temperature reservoir at $T_{\text{c}}$ when the ideal gas expands isothermally. The gas is then compressed adiabatically until its temperature reaches $T_{\text{h}},$ after which an isothermal compression of the gas results in heat $Q_{\text{h}}$ being discarded to a high-temperature reservoir at $T_{\text{h}}.$ Finally, the cycle is completed by an adiabatic expansion of the gas, causing its temperature to drop to $T_{\text{c}}.$

Figure 4.13 The work done on the gas in one cycle of the Carnot refrigerator is shown and given by the area enclosed by the loop MPONM.

The work done on the ideal gas is equal to the area enclosed by the path of the pV diagram. From the first law, this work is given by

An analysis just like the analysis done for the Carnot engine gives

When combined with Equation 4.3, this yields

for the coefficient of performance of the ideal-gas Carnot refrigerator. Similarly, we can work out the coefficient of performance for a Carnot heat pump as

We have just found equations representing the efficiency of a Carnot engine and the coefficient of performance of a Carnot refrigerator or a Carnot heat pump, assuming an ideal gas for the working substance in both devices. However, these equations are more general than their derivations imply. We will soon show that they are both valid no matter what the working substance is.

Carnot summarized his study of the Carnot engine and Carnot cycle into what is now known as Carnot’s principle:

This principle can be viewed as another statement of the second law of thermodynamics and can be shown to be equivalent to the Kelvin statement and the Clausius statement.

In terms of energy costs, the heat pump is a very economical means for heating buildings (Figure 4.14). Contrast this method with turning electrical energy directly into heat with resistive heating elements. In this case, one unit of electrical energy furnishes at most only one unit of heat. Unfortunately, heat pumps have problems that do limit their usefulness. They are quite expensive to purchase compared to resistive heating elements, and, as the performance coefficient for a Carnot heat pump shows, they become less effective as the outside temperature decreases. In fact, below about $\mathrm{–10}\text{°C}$, the heat they furnish is less than the energy used to operate them.

Figure 4.14 A photograph of a heat pump (large box) located outside a house. This heat pump is located in a warm climate area, like the southern United States, since it would be far too inefficient located in the northern half of the United States. (credit: modification of work by Peter Stevens)