Key Terms
- adiabatic process
- process during which no heat is transferred to or from the system
- boundary
- imagined walls that separate the system and its surroundings
- closed system
- system that is mechanically and thermally isolated from its environment
- cyclic process
- process in which the state of the system at the end is same as the state at the beginning
- environment
- outside of the system being studied
- equation of state
- describes properties of matter under given physical conditions
- equilibrium
- thermal balance established between two objects or parts within a system
- extensive variable
- variable that is proportional to the amount of matter in the system
- first law of thermodynamics
- the change in internal energy for any transition between two equilibrium states is
- intensive variable
- variable that is independent of the amount of matter in the system
- internal energy
- average of the total mechanical energy of all the molecules or entities in the system
- isobaric process
- process during which the system’s pressure does not change
- isochoric process
- process during which the system’s volume does not change
- isothermal process
- process during which the system’s temperature remains constant
- molar heat capacity at constant pressure
- quantifies the ratio of the amount of heat added removed to the temperature while measuring at constant pressure
- molar heat capacity at constant volume
- quantifies the ratio of the amount of heat added removed to the temperature while measuring at constant volume
- open system
- system that can exchange energy and/or matter with its surroundings
- quasi-static process
- evolution of a system that goes so slowly that the system involved is always in thermodynamic equilibrium
- reversible process
- process that can be reverted to restore both the system and its environment back to their original states together
- surroundings
- environment that interacts with an open system
- thermodynamic process
- manner in which a state of a system can change from initial state to final state
- thermodynamic system
- object and focus of thermodynamic study