Skip to ContentGo to accessibility page

Key Terms

adiabatic process
process during which no heat is transferred to or from the system
boundary
imagined walls that separate the system and its surroundings
closed system
system that is mechanically and thermally isolated from its environment
cyclic process
process in which the state of the system at the end is same as the state at the beginning
environment
outside of the system being studied
equation of state
describes properties of matter under given physical conditions
equilibrium
thermal balance established between two objects or parts within a system
extensive variable
variable that is proportional to the amount of matter in the system
first law of thermodynamics
the change in internal energy for any transition between two equilibrium states is ΔEint=QWΔEint=QW
intensive variable
variable that is independent of the amount of matter in the system
internal energy
average of the total mechanical energy of all the molecules or entities in the system
isobaric process
process during which the system’s pressure does not change
isochoric process
process during which the system’s volume does not change
isothermal process
process during which the system’s temperature remains constant
molar heat capacity at constant pressure
quantifies the ratio of the amount of heat added removed to the temperature while measuring at constant pressure
molar heat capacity at constant volume
quantifies the ratio of the amount of heat added removed to the temperature while measuring at constant volume
open system
system that can exchange energy and/or matter with its surroundings
quasi-static process
evolution of a system that goes so slowly that the system involved is always in thermodynamic equilibrium
reversible process
process that can be reverted to restore both the system and its environment back to their original states together
surroundings
environment that interacts with an open system
thermodynamic process
manner in which a state of a system can change from initial state to final state
thermodynamic system
object and focus of thermodynamic study
Citation/Attribution
Reuse and redistribution of this content in digital or print format:
  • This book may not be used in the training of large language models or otherwise be ingested into large language models or generative AI offerings without OpenStax's prior written permission.
  • This book uses the Creative Commons Attribution-NonCommercial-ShareAlike License, which means that you can reuse and modify the material only for noncommercial purposes, must attribute OpenStax, and must distribute any derivative works under the same license.
  • Any commercial printing of this textbook, including using a local or custom printer, must be approved by OpenStax, and proper citation provided.
  • OpenStax-copyrighted images, activities, assessments, and similar components of this book are subject to the same licensing – CC-BY-NC-SA. They can be used for noncommercial purposes with attribution. Commercial use requires permission.
  • Permission requests: Anyone who intends to incorporate this content (including text, images, and other components) into large language models, use it in AI offerings, use it commercially (including in print), and/or has questions about another use case is welcome to complete our reuse request form.
Attribution information
  • If you are redistributing all or part of this book in a noncommercial print format, then you must include on every physical page the following attribution:

    Access for free at https://openstax.org/books/university-physics-volume-2/pages/1-introduction

  • If you are redistributing all or part of this book in a noncommercial digital format, then for every page that includes OpenStax content, you must license the derivative work under the same CC-BY-NC-SA license as the original, and include on every digital page view the following attribution:

    Access for free at https://openstax.org/books/university-physics-volume-2/pages/1-introduction

Citation information

The information below includes the information needed to generate citations in most major styles (APA, MLA, etc.); you must reformat and organize the information as needed to fit the requirements of the style. Use the information below to generate a citation. We recommend using a citation tool such as this one.

© Jun 11, 2026 OpenStax. Textbook content produced by OpenStax is licensed under a Creative Commons Attribution-NonCommercial-ShareAlike License. The OpenStax name, OpenStax logo, OpenStax book covers, OpenStax CNX name, and OpenStax CNX logo, and Rice University name, and Rice University logo trademarks, or wordmarks are not subject to the Creative Commons license and may not be reproduced without the prior and express written consent of Rice University.