Problem
10-3
Chiral: 1-chloro-2-methylpentane, 3-chloro-2-methylpentane, 2-chloro-4-methylpentane Achiral: 2-chloro-2-methylpentane, 1-chloro-4-methylpentane
Problem
10-4
1-Chloro-2-methylbutane (29%), 1-chloro-3-methylbutane (14%), 2-chloro-2-methylbutane (24%), 2-chloro-3-methylbutane (33%)
Problem
10-6
The intermediate allylic radical reacts at the more accessible site and gives the more highly substituted double bond.
Problem
10-9
Both reactions occur.
Problem
10-10
React Grignard reagent with D2O.