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College Physics for AP® Courses

29.1 Quantization of Energy

College Physics for AP® Courses29.1 Quantization of Energy
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  1. Preface
  2. 1 Introduction: The Nature of Science and Physics
    1. Connection for AP® Courses
    2. 1.1 Physics: An Introduction
    3. 1.2 Physical Quantities and Units
    4. 1.3 Accuracy, Precision, and Significant Figures
    5. 1.4 Approximation
    6. Glossary
    7. Section Summary
    8. Conceptual Questions
    9. Problems & Exercises
  3. 2 Kinematics
    1. Connection for AP® Courses
    2. 2.1 Displacement
    3. 2.2 Vectors, Scalars, and Coordinate Systems
    4. 2.3 Time, Velocity, and Speed
    5. 2.4 Acceleration
    6. 2.5 Motion Equations for Constant Acceleration in One Dimension
    7. 2.6 Problem-Solving Basics for One Dimensional Kinematics
    8. 2.7 Falling Objects
    9. 2.8 Graphical Analysis of One Dimensional Motion
    10. Glossary
    11. Section Summary
    12. Conceptual Questions
    13. Problems & Exercises
    14. Test Prep for AP® Courses
  4. 3 Two-Dimensional Kinematics
    1. Connection for AP® Courses
    2. 3.1 Kinematics in Two Dimensions: An Introduction
    3. 3.2 Vector Addition and Subtraction: Graphical Methods
    4. 3.3 Vector Addition and Subtraction: Analytical Methods
    5. 3.4 Projectile Motion
    6. 3.5 Addition of Velocities
    7. Glossary
    8. Section Summary
    9. Conceptual Questions
    10. Problems & Exercises
    11. Test Prep for AP® Courses
  5. 4 Dynamics: Force and Newton's Laws of Motion
    1. Connection for AP® Courses
    2. 4.1 Development of Force Concept
    3. 4.2 Newton's First Law of Motion: Inertia
    4. 4.3 Newton's Second Law of Motion: Concept of a System
    5. 4.4 Newton's Third Law of Motion: Symmetry in Forces
    6. 4.5 Normal, Tension, and Other Examples of Force
    7. 4.6 Problem-Solving Strategies
    8. 4.7 Further Applications of Newton's Laws of Motion
    9. 4.8 Extended Topic: The Four Basic Forces—An Introduction
    10. Glossary
    11. Section Summary
    12. Conceptual Questions
    13. Problems & Exercises
    14. Test Prep for AP® Courses
  6. 5 Further Applications of Newton's Laws: Friction, Drag, and Elasticity
    1. Connection for AP® Courses
    2. 5.1 Friction
    3. 5.2 Drag Forces
    4. 5.3 Elasticity: Stress and Strain
    5. Glossary
    6. Section Summary
    7. Conceptual Questions
    8. Problems & Exercises
    9. Test Prep for AP® Courses
  7. 6 Gravitation and Uniform Circular Motion
    1. Connection for AP® Courses
    2. 6.1 Rotation Angle and Angular Velocity
    3. 6.2 Centripetal Acceleration
    4. 6.3 Centripetal Force
    5. 6.4 Fictitious Forces and Non-inertial Frames: The Coriolis Force
    6. 6.5 Newton's Universal Law of Gravitation
    7. 6.6 Satellites and Kepler's Laws: An Argument for Simplicity
    8. Glossary
    9. Section Summary
    10. Conceptual Questions
    11. Problems & Exercises
    12. Test Prep for AP® Courses
  8. 7 Work, Energy, and Energy Resources
    1. Connection for AP® Courses
    2. 7.1 Work: The Scientific Definition
    3. 7.2 Kinetic Energy and the Work-Energy Theorem
    4. 7.3 Gravitational Potential Energy
    5. 7.4 Conservative Forces and Potential Energy
    6. 7.5 Nonconservative Forces
    7. 7.6 Conservation of Energy
    8. 7.7 Power
    9. 7.8 Work, Energy, and Power in Humans
    10. 7.9 World Energy Use
    11. Glossary
    12. Section Summary
    13. Conceptual Questions
    14. Problems & Exercises
    15. Test Prep for AP® Courses
  9. 8 Linear Momentum and Collisions
    1. Connection for AP® courses
    2. 8.1 Linear Momentum and Force
    3. 8.2 Impulse
    4. 8.3 Conservation of Momentum
    5. 8.4 Elastic Collisions in One Dimension
    6. 8.5 Inelastic Collisions in One Dimension
    7. 8.6 Collisions of Point Masses in Two Dimensions
    8. 8.7 Introduction to Rocket Propulsion
    9. Glossary
    10. Section Summary
    11. Conceptual Questions
    12. Problems & Exercises
    13. Test Prep for AP® Courses
  10. 9 Statics and Torque
    1. Connection for AP® Courses
    2. 9.1 The First Condition for Equilibrium
    3. 9.2 The Second Condition for Equilibrium
    4. 9.3 Stability
    5. 9.4 Applications of Statics, Including Problem-Solving Strategies
    6. 9.5 Simple Machines
    7. 9.6 Forces and Torques in Muscles and Joints
    8. Glossary
    9. Section Summary
    10. Conceptual Questions
    11. Problems & Exercises
    12. Test Prep for AP® Courses
  11. 10 Rotational Motion and Angular Momentum
    1. Connection for AP® Courses
    2. 10.1 Angular Acceleration
    3. 10.2 Kinematics of Rotational Motion
    4. 10.3 Dynamics of Rotational Motion: Rotational Inertia
    5. 10.4 Rotational Kinetic Energy: Work and Energy Revisited
    6. 10.5 Angular Momentum and Its Conservation
    7. 10.6 Collisions of Extended Bodies in Two Dimensions
    8. 10.7 Gyroscopic Effects: Vector Aspects of Angular Momentum
    9. Glossary
    10. Section Summary
    11. Conceptual Questions
    12. Problems & Exercises
    13. Test Prep for AP® Courses
  12. 11 Fluid Statics
    1. Connection for AP® Courses
    2. 11.1 What Is a Fluid?
    3. 11.2 Density
    4. 11.3 Pressure
    5. 11.4 Variation of Pressure with Depth in a Fluid
    6. 11.5 Pascal’s Principle
    7. 11.6 Gauge Pressure, Absolute Pressure, and Pressure Measurement
    8. 11.7 Archimedes’ Principle
    9. 11.8 Cohesion and Adhesion in Liquids: Surface Tension and Capillary Action
    10. 11.9 Pressures in the Body
    11. Glossary
    12. Section Summary
    13. Conceptual Questions
    14. Problems & Exercises
    15. Test Prep for AP® Courses
  13. 12 Fluid Dynamics and Its Biological and Medical Applications
    1. Connection for AP® Courses
    2. 12.1 Flow Rate and Its Relation to Velocity
    3. 12.2 Bernoulli’s Equation
    4. 12.3 The Most General Applications of Bernoulli’s Equation
    5. 12.4 Viscosity and Laminar Flow; Poiseuille’s Law
    6. 12.5 The Onset of Turbulence
    7. 12.6 Motion of an Object in a Viscous Fluid
    8. 12.7 Molecular Transport Phenomena: Diffusion, Osmosis, and Related Processes
    9. Glossary
    10. Section Summary
    11. Conceptual Questions
    12. Problems & Exercises
    13. Test Prep for AP® Courses
  14. 13 Temperature, Kinetic Theory, and the Gas Laws
    1. Connection for AP® Courses
    2. 13.1 Temperature
    3. 13.2 Thermal Expansion of Solids and Liquids
    4. 13.3 The Ideal Gas Law
    5. 13.4 Kinetic Theory: Atomic and Molecular Explanation of Pressure and Temperature
    6. 13.5 Phase Changes
    7. 13.6 Humidity, Evaporation, and Boiling
    8. Glossary
    9. Section Summary
    10. Conceptual Questions
    11. Problems & Exercises
    12. Test Prep for AP® Courses
  15. 14 Heat and Heat Transfer Methods
    1. Connection for AP® Courses
    2. 14.1 Heat
    3. 14.2 Temperature Change and Heat Capacity
    4. 14.3 Phase Change and Latent Heat
    5. 14.4 Heat Transfer Methods
    6. 14.5 Conduction
    7. 14.6 Convection
    8. 14.7 Radiation
    9. Glossary
    10. Section Summary
    11. Conceptual Questions
    12. Problems & Exercises
    13. Test Prep for AP® Courses
  16. 15 Thermodynamics
    1. Connection for AP® Courses
    2. 15.1 The First Law of Thermodynamics
    3. 15.2 The First Law of Thermodynamics and Some Simple Processes
    4. 15.3 Introduction to the Second Law of Thermodynamics: Heat Engines and Their Efficiency
    5. 15.4 Carnot’s Perfect Heat Engine: The Second Law of Thermodynamics Restated
    6. 15.5 Applications of Thermodynamics: Heat Pumps and Refrigerators
    7. 15.6 Entropy and the Second Law of Thermodynamics: Disorder and the Unavailability of Energy
    8. 15.7 Statistical Interpretation of Entropy and the Second Law of Thermodynamics: The Underlying Explanation
    9. Glossary
    10. Section Summary
    11. Conceptual Questions
    12. Problems & Exercises
    13. Test Prep for AP® Courses
  17. 16 Oscillatory Motion and Waves
    1. Connection for AP® Courses
    2. 16.1 Hooke’s Law: Stress and Strain Revisited
    3. 16.2 Period and Frequency in Oscillations
    4. 16.3 Simple Harmonic Motion: A Special Periodic Motion
    5. 16.4 The Simple Pendulum
    6. 16.5 Energy and the Simple Harmonic Oscillator
    7. 16.6 Uniform Circular Motion and Simple Harmonic Motion
    8. 16.7 Damped Harmonic Motion
    9. 16.8 Forced Oscillations and Resonance
    10. 16.9 Waves
    11. 16.10 Superposition and Interference
    12. 16.11 Energy in Waves: Intensity
    13. Glossary
    14. Section Summary
    15. Conceptual Questions
    16. Problems & Exercises
    17. Test Prep for AP® Courses
  18. 17 Physics of Hearing
    1. Connection for AP® Courses
    2. 17.1 Sound
    3. 17.2 Speed of Sound, Frequency, and Wavelength
    4. 17.3 Sound Intensity and Sound Level
    5. 17.4 Doppler Effect and Sonic Booms
    6. 17.5 Sound Interference and Resonance: Standing Waves in Air Columns
    7. 17.6 Hearing
    8. 17.7 Ultrasound
    9. Glossary
    10. Section Summary
    11. Conceptual Questions
    12. Problems & Exercises
    13. Test Prep for AP® Courses
  19. 18 Electric Charge and Electric Field
    1. Connection for AP® Courses
    2. 18.1 Static Electricity and Charge: Conservation of Charge
    3. 18.2 Conductors and Insulators
    4. 18.3 Conductors and Electric Fields in Static Equilibrium
    5. 18.4 Coulomb’s Law
    6. 18.5 Electric Field: Concept of a Field Revisited
    7. 18.6 Electric Field Lines: Multiple Charges
    8. 18.7 Electric Forces in Biology
    9. 18.8 Applications of Electrostatics
    10. Glossary
    11. Section Summary
    12. Conceptual Questions
    13. Problems & Exercises
    14. Test Prep for AP® Courses
  20. 19 Electric Potential and Electric Field
    1. Connection for AP® Courses
    2. 19.1 Electric Potential Energy: Potential Difference
    3. 19.2 Electric Potential in a Uniform Electric Field
    4. 19.3 Electrical Potential Due to a Point Charge
    5. 19.4 Equipotential Lines
    6. 19.5 Capacitors and Dielectrics
    7. 19.6 Capacitors in Series and Parallel
    8. 19.7 Energy Stored in Capacitors
    9. Glossary
    10. Section Summary
    11. Conceptual Questions
    12. Problems & Exercises
    13. Test Prep for AP® Courses
  21. 20 Electric Current, Resistance, and Ohm's Law
    1. Connection for AP® Courses
    2. 20.1 Current
    3. 20.2 Ohm’s Law: Resistance and Simple Circuits
    4. 20.3 Resistance and Resistivity
    5. 20.4 Electric Power and Energy
    6. 20.5 Alternating Current versus Direct Current
    7. 20.6 Electric Hazards and the Human Body
    8. 20.7 Nerve Conduction–Electrocardiograms
    9. Glossary
    10. Section Summary
    11. Conceptual Questions
    12. Problems & Exercises
    13. Test Prep for AP® Courses
  22. 21 Circuits, Bioelectricity, and DC Instruments
    1. Connection for AP® Courses
    2. 21.1 Resistors in Series and Parallel
    3. 21.2 Electromotive Force: Terminal Voltage
    4. 21.3 Kirchhoff’s Rules
    5. 21.4 DC Voltmeters and Ammeters
    6. 21.5 Null Measurements
    7. 21.6 DC Circuits Containing Resistors and Capacitors
    8. Glossary
    9. Section Summary
    10. Conceptual Questions
    11. Problems & Exercises
    12. Test Prep for AP® Courses
  23. 22 Magnetism
    1. Connection for AP® Courses
    2. 22.1 Magnets
    3. 22.2 Ferromagnets and Electromagnets
    4. 22.3 Magnetic Fields and Magnetic Field Lines
    5. 22.4 Magnetic Field Strength: Force on a Moving Charge in a Magnetic Field
    6. 22.5 Force on a Moving Charge in a Magnetic Field: Examples and Applications
    7. 22.6 The Hall Effect
    8. 22.7 Magnetic Force on a Current-Carrying Conductor
    9. 22.8 Torque on a Current Loop: Motors and Meters
    10. 22.9 Magnetic Fields Produced by Currents: Ampere’s Law
    11. 22.10 Magnetic Force between Two Parallel Conductors
    12. 22.11 More Applications of Magnetism
    13. Glossary
    14. Section Summary
    15. Conceptual Questions
    16. Problems & Exercises
    17. Test Prep for AP® Courses
  24. 23 Electromagnetic Induction, AC Circuits, and Electrical Technologies
    1. Connection for AP® Courses
    2. 23.1 Induced Emf and Magnetic Flux
    3. 23.2 Faraday’s Law of Induction: Lenz’s Law
    4. 23.3 Motional Emf
    5. 23.4 Eddy Currents and Magnetic Damping
    6. 23.5 Electric Generators
    7. 23.6 Back Emf
    8. 23.7 Transformers
    9. 23.8 Electrical Safety: Systems and Devices
    10. 23.9 Inductance
    11. 23.10 RL Circuits
    12. 23.11 Reactance, Inductive and Capacitive
    13. 23.12 RLC Series AC Circuits
    14. Glossary
    15. Section Summary
    16. Conceptual Questions
    17. Problems & Exercises
    18. Test Prep for AP® Courses
  25. 24 Electromagnetic Waves
    1. Connection for AP® Courses
    2. 24.1 Maxwell’s Equations: Electromagnetic Waves Predicted and Observed
    3. 24.2 Production of Electromagnetic Waves
    4. 24.3 The Electromagnetic Spectrum
    5. 24.4 Energy in Electromagnetic Waves
    6. Glossary
    7. Section Summary
    8. Conceptual Questions
    9. Problems & Exercises
    10. Test Prep for AP® Courses
  26. 25 Geometric Optics
    1. Connection for AP® Courses
    2. 25.1 The Ray Aspect of Light
    3. 25.2 The Law of Reflection
    4. 25.3 The Law of Refraction
    5. 25.4 Total Internal Reflection
    6. 25.5 Dispersion: The Rainbow and Prisms
    7. 25.6 Image Formation by Lenses
    8. 25.7 Image Formation by Mirrors
    9. Glossary
    10. Section Summary
    11. Conceptual Questions
    12. Problems & Exercises
    13. Test Prep for AP® Courses
  27. 26 Vision and Optical Instruments
    1. Connection for AP® Courses
    2. 26.1 Physics of the Eye
    3. 26.2 Vision Correction
    4. 26.3 Color and Color Vision
    5. 26.4 Microscopes
    6. 26.5 Telescopes
    7. 26.6 Aberrations
    8. Glossary
    9. Section Summary
    10. Conceptual Questions
    11. Problems & Exercises
    12. Test Prep for AP® Courses
  28. 27 Wave Optics
    1. Connection for AP® Courses
    2. 27.1 The Wave Aspect of Light: Interference
    3. 27.2 Huygens's Principle: Diffraction
    4. 27.3 Young’s Double Slit Experiment
    5. 27.4 Multiple Slit Diffraction
    6. 27.5 Single Slit Diffraction
    7. 27.6 Limits of Resolution: The Rayleigh Criterion
    8. 27.7 Thin Film Interference
    9. 27.8 Polarization
    10. 27.9 *Extended Topic* Microscopy Enhanced by the Wave Characteristics of Light
    11. Glossary
    12. Section Summary
    13. Conceptual Questions
    14. Problems & Exercises
    15. Test Prep for AP® Courses
  29. 28 Special Relativity
    1. Connection for AP® Courses
    2. 28.1 Einstein’s Postulates
    3. 28.2 Simultaneity And Time Dilation
    4. 28.3 Length Contraction
    5. 28.4 Relativistic Addition of Velocities
    6. 28.5 Relativistic Momentum
    7. 28.6 Relativistic Energy
    8. Glossary
    9. Section Summary
    10. Conceptual Questions
    11. Problems & Exercises
    12. Test Prep for AP® Courses
  30. 29 Introduction to Quantum Physics
    1. Connection for AP® Courses
    2. 29.1 Quantization of Energy
    3. 29.2 The Photoelectric Effect
    4. 29.3 Photon Energies and the Electromagnetic Spectrum
    5. 29.4 Photon Momentum
    6. 29.5 The Particle-Wave Duality
    7. 29.6 The Wave Nature of Matter
    8. 29.7 Probability: The Heisenberg Uncertainty Principle
    9. 29.8 The Particle-Wave Duality Reviewed
    10. Glossary
    11. Section Summary
    12. Conceptual Questions
    13. Problems & Exercises
    14. Test Prep for AP® Courses
  31. 30 Atomic Physics
    1. Connection for AP® Courses
    2. 30.1 Discovery of the Atom
    3. 30.2 Discovery of the Parts of the Atom: Electrons and Nuclei
    4. 30.3 Bohr’s Theory of the Hydrogen Atom
    5. 30.4 X Rays: Atomic Origins and Applications
    6. 30.5 Applications of Atomic Excitations and De-Excitations
    7. 30.6 The Wave Nature of Matter Causes Quantization
    8. 30.7 Patterns in Spectra Reveal More Quantization
    9. 30.8 Quantum Numbers and Rules
    10. 30.9 The Pauli Exclusion Principle
    11. Glossary
    12. Section Summary
    13. Conceptual Questions
    14. Problems & Exercises
    15. Test Prep for AP® Courses
  32. 31 Radioactivity and Nuclear Physics
    1. Connection for AP® Courses
    2. 31.1 Nuclear Radioactivity
    3. 31.2 Radiation Detection and Detectors
    4. 31.3 Substructure of the Nucleus
    5. 31.4 Nuclear Decay and Conservation Laws
    6. 31.5 Half-Life and Activity
    7. 31.6 Binding Energy
    8. 31.7 Tunneling
    9. Glossary
    10. Section Summary
    11. Conceptual Questions
    12. Problems & Exercises
    13. Test Prep for AP® Courses
  33. 32 Medical Applications of Nuclear Physics
    1. Connection for AP® Courses
    2. 32.1 Medical Imaging and Diagnostics
    3. 32.2 Biological Effects of Ionizing Radiation
    4. 32.3 Therapeutic Uses of Ionizing Radiation
    5. 32.4 Food Irradiation
    6. 32.5 Fusion
    7. 32.6 Fission
    8. 32.7 Nuclear Weapons
    9. Glossary
    10. Section Summary
    11. Conceptual Questions
    12. Problems & Exercises
    13. Test Prep for AP® Courses
  34. 33 Particle Physics
    1. Connection for AP® Courses
    2. 33.1 The Yukawa Particle and the Heisenberg Uncertainty Principle Revisited
    3. 33.2 The Four Basic Forces
    4. 33.3 Accelerators Create Matter from Energy
    5. 33.4 Particles, Patterns, and Conservation Laws
    6. 33.5 Quarks: Is That All There Is?
    7. 33.6 GUTs: The Unification of Forces
    8. Glossary
    9. Section Summary
    10. Conceptual Questions
    11. Problems & Exercises
    12. Test Prep for AP® Courses
  35. 34 Frontiers of Physics
    1. Connection for AP® Courses
    2. 34.1 Cosmology and Particle Physics
    3. 34.2 General Relativity and Quantum Gravity
    4. 34.3 Superstrings
    5. 34.4 Dark Matter and Closure
    6. 34.5 Complexity and Chaos
    7. 34.6 High-Temperature Superconductors
    8. 34.7 Some Questions We Know to Ask
    9. Glossary
    10. Section Summary
    11. Conceptual Questions
    12. Problems & Exercises
  36. A | Atomic Masses
  37. B | Selected Radioactive Isotopes
  38. C | Useful Information
  39. D | Glossary of Key Symbols and Notation
  40. Answer Key
    1. Chapter 1
    2. Chapter 2
    3. Chapter 3
    4. Chapter 4
    5. Chapter 5
    6. Chapter 6
    7. Chapter 7
    8. Chapter 8
    9. Chapter 9
    10. Chapter 10
    11. Chapter 11
    12. Chapter 12
    13. Chapter 13
    14. Chapter 14
    15. Chapter 15
    16. Chapter 16
    17. Chapter 17
    18. Chapter 18
    19. Chapter 19
    20. Chapter 20
    21. Chapter 21
    22. Chapter 22
    23. Chapter 23
    24. Chapter 24
    25. Chapter 25
    26. Chapter 26
    27. Chapter 27
    28. Chapter 28
    29. Chapter 29
    30. Chapter 30
    31. Chapter 31
    32. Chapter 32
    33. Chapter 33
    34. Chapter 34
  41. Index

Learning Objectives

By the end of this section, you will be able to:

  • Explain Max Planck’s contribution to the development of quantum mechanics.
  • Explain why atomic spectra indicate quantization.

The information presented in this section supports the following AP® learning objectives and science practices:

  • 5.B.8.1 The student is able to describe emission or absorption spectra associated with electronic or nuclear transitions as transitions between allowed energy states of the atom in terms of the principle of energy conservation, including characterization of the frequency of radiation emitted or absorbed. (S.P. 1.2, 7.2)

Planck’s Contribution

Energy is quantized in some systems, meaning that the system can have only certain energies and not a continuum of energies, unlike the classical case. This would be like having only certain speeds at which a car can travel because its kinetic energy can have only certain values. We also find that some forms of energy transfer take place with discrete lumps of energy. While most of us are familiar with the quantization of matter into lumps called atoms, molecules, and the like, we are less aware that energy, too, can be quantized. Some of the earliest clues about the necessity of quantum mechanics over classical physics came from the quantization of energy.

The blackbody radiation graph of E M radiation intensity versus wavelengths is shown, with the visible band represented as vertical colored strip marked on x axis. Wavelength is along x axis and E M radiation intensity is along y axis. The variation of E M radiation intensity is shown by three curves that start at origin, rise up to their highest point and then drop toward the x axis smoothly, and finally extend parallel to the x axis. There are three curves for three different temperatures, and each has a different peak for radiation intensity. As the temperature decreases, the peak of the black body radiation curves moves to a lower radiation intensity and longer wavelength.
Figure 29.3 Graphs of blackbody radiation (from an ideal radiator) at three different radiator temperatures. The intensity or rate of radiation emission increases dramatically with temperature, and the peak of the spectrum shifts toward the visible and ultraviolet parts of the spectrum. The shape of the spectrum cannot be described with classical physics.

Where is the quantization of energy observed? Let us begin by considering the emission and absorption of electromagnetic (EM) radiation. The EM spectrum radiated by a hot solid is linked directly to the solid’s temperature. (See Figure 29.3.) An ideal radiator is one that has an emissivity of 1 at all wavelengths and, thus, is jet black. Ideal radiators are therefore called blackbodies, and their EM radiation is called blackbody radiation. It was discussed that the total intensity of the radiation varies as T4,T4, size 12{T rSup { size 8{4} } } {} the fourth power of the absolute temperature of the body, and that the peak of the spectrum shifts to shorter wavelengths at higher temperatures. All of this seems quite continuous, but it was the curve of the spectrum of intensity versus wavelength that gave a clue that the energies of the atoms in the solid are quantized. In fact, providing a theoretical explanation for the experimentally measured shape of the spectrum was a mystery at the turn of the century. When this “ultraviolet catastrophe” was eventually solved, the answers led to new technologies such as computers and the sophisticated imaging techniques described in earlier chapters. Once again, physics as an enabling science changed the way we live.

The German physicist Max Planck (1858–1947) used the idea that atoms and molecules in a body act like oscillators to absorb and emit radiation. The energies of the oscillating atoms and molecules had to be quantized to correctly describe the shape of the blackbody spectrum. Planck deduced that the energy of an oscillator having a frequency ff size 12{f} {} is given by

E=n+12hf.E=n+12hf. size 12{E= left (n+ { { size 8{1} } over { size 8{2} } } right ) ital "hf"} {}
29.1

Here nn size 12{n} {} is any nonnegative integer (0, 1, 2, 3, …). The symbol hh size 12{h} {} stands for Planck’s constant, given by

h=6.626× 10–34 J s.h=6.626× 10–34 J s. size 12{h = 6 "." "626" times " 10" rSup { size 8{"–34"} } " J " cdot " s"} {}
29.2

The equation E=n+12hfE=n+12hf size 12{E= left (n+ { { size 8{1} } over { size 8{2} } } right ) ital "hf"} {} means that an oscillator having a frequency ff size 12{f} {} (emitting and absorbing EM radiation of frequency ff size 12{f} {}) can have its energy increase or decrease only in discrete steps of size

ΔE=hf.ΔE=hf. size 12{ΔE = ital "hf"} {}
29.3

It might be helpful to mention some macroscopic analogies of this quantization of energy phenomena. This is like a pendulum that has a characteristic oscillation frequency but can swing with only certain amplitudes. Quantization of energy also resembles a standing wave on a string that allows only particular harmonics described by integers. It is also similar to going up and down a hill using discrete stair steps rather than being able to move up and down a continuous slope. Your potential energy takes on discrete values as you move from step to step.

Using the quantization of oscillators, Planck was able to correctly describe the experimentally known shape of the blackbody spectrum. This was the first indication that energy is sometimes quantized on a small scale and earned him the Nobel Prize in Physics in 1918. Although Planck’s theory comes from observations of a macroscopic object, its analysis is based on atoms and molecules. It was such a revolutionary departure from classical physics that Planck himself was reluctant to accept his own idea that energy states are not continuous. The general acceptance of Planck’s energy quantization was greatly enhanced by Einstein’s explanation of the photoelectric effect (discussed in the next section), which took energy quantization a step further. Planck was fully involved in the development of both early quantum mechanics and relativity. He quickly embraced Einstein’s special relativity, published in 1905, and in 1906 Planck was the first to suggest the correct formula for relativistic momentum, p=γmup=γmu size 12{p= ital "γmu"} {}.

A photo of German physicist Max Plank is shown.
Figure 29.4 The German physicist Max Planck had a major influence on the early development of quantum mechanics, being the first to recognize that energy is sometimes quantized. Planck also made important contributions to special relativity and classical physics. (credit: Library of Congress, Prints and Photographs Division via Wikimedia Commons)

Note that Planck’s constant hh size 12{h} {} is a very small number. So for an infrared frequency of 1014Hz1014Hz size 12{"10" rSup { size 8{"14"} } `"Hz"} {} being emitted by a blackbody, for example, the difference between energy levels is only ΔE=hf= (6.63 × 10–34 J·s)(1014 Hz) = 6.63 × 10–20 J,ΔE=hf= (6.63 × 10–34 J·s)(1014 Hz) = 6.63 × 10–20 J, size 12{ΔE = ital "hf""= " \( 6 "." "63 " times " 10" rSup { size 8{"–34"} } " J·s" \) \( "10" rSup { size 8{"14"} } " Hz" \) " = 6" "." "63 " times " 10" rSup { size 8{"–20"} } " J"} {} or about 0.4 eV. This 0.4 eV of energy is significant compared with typical atomic energies, which are on the order of an electron volt, or thermal energies, which are typically fractions of an electron volt. But on a macroscopic or classical scale, energies are typically on the order of joules. Even if macroscopic energies are quantized, the quantum steps are too small to be noticed. This is an example of the correspondence principle. For a large object, quantum mechanics produces results indistinguishable from those of classical physics.

Atomic Spectra

Now let us turn our attention to the emission and absorption of EM radiation by gases. The Sun is the most common example of a body containing gases emitting an EM spectrum that includes visible light. We also see examples in neon signs and candle flames. Studies of emissions of hot gases began more than two centuries ago, and it was soon recognized that these emission spectra contained huge amounts of information. The type of gas and its temperature, for example, could be determined. We now know that these EM emissions come from electrons transitioning between energy levels in individual atoms and molecules; thus, they are called atomic spectra. Atomic spectra remain an important analytical tool today. Figure 29.5 shows an example of an emission spectrum obtained by passing an electric discharge through a material. One of the most important characteristics of these spectra is that they are discrete. By this we mean that only certain wavelengths, and hence frequencies, are emitted. This is called a line spectrum. If frequency and energy are associated as ΔE=hf,ΔE=hf, size 12{ΔE = ital "hf"} {} the energies of the electrons in the emitting atoms and molecules are quantized. This is discussed in more detail later in this chapter.

Emission spectrum of oxygen is shown as a band containing all colors with some distinct colors as discrete bold lines.
Figure 29.5 Emission spectrum of oxygen. When an electrical discharge is passed through a substance, its atoms and molecules absorb energy, which is reemitted as EM radiation. The discrete nature of these emissions implies that the energy states of the atoms and molecules are quantized. Such atomic spectra were used as analytical tools for many decades before it was understood why they are quantized. (credit: Teravolt, Wikimedia Commons)

It was a major puzzle that atomic spectra are quantized. Some of the best minds of 19th-century science failed to explain why this might be. Not until the second decade of the 20th century did an answer based on quantum mechanics begin to emerge. Again a macroscopic or classical body of gas was involved in the studies, but the effect, as we shall see, is due to individual atoms and molecules.

PhET Explorations: Models of the Hydrogen Atom

How did scientists figure out the structure of atoms without looking at them? Try out different models by shooting light at the atom. Check how the prediction of the model matches the experimental results.

Figure 29.6 Models of the Hydrogen Atom
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