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Chemistry

Summary

ChemistrySummary
  1. Preface
  2. 1 Essential Ideas
    1. Introduction
    2. 1.1 Chemistry in Context
    3. 1.2 Phases and Classification of Matter
    4. 1.3 Physical and Chemical Properties
    5. 1.4 Measurements
    6. 1.5 Measurement Uncertainty, Accuracy, and Precision
    7. 1.6 Mathematical Treatment of Measurement Results
    8. Key Terms
    9. Key Equations
    10. Summary
    11. Exercises
  3. 2 Atoms, Molecules, and Ions
    1. Introduction
    2. 2.1 Early Ideas in Atomic Theory
    3. 2.2 Evolution of Atomic Theory
    4. 2.3 Atomic Structure and Symbolism
    5. 2.4 Chemical Formulas
    6. 2.5 The Periodic Table
    7. 2.6 Molecular and Ionic Compounds
    8. 2.7 Chemical Nomenclature
    9. Key Terms
    10. Key Equations
    11. Summary
    12. Exercises
  4. 3 Composition of Substances and Solutions
    1. Introduction
    2. 3.1 Formula Mass and the Mole Concept
    3. 3.2 Determining Empirical and Molecular Formulas
    4. 3.3 Molarity
    5. 3.4 Other Units for Solution Concentrations
    6. Key Terms
    7. Key Equations
    8. Summary
    9. Exercises
  5. 4 Stoichiometry of Chemical Reactions
    1. Introduction
    2. 4.1 Writing and Balancing Chemical Equations
    3. 4.2 Classifying Chemical Reactions
    4. 4.3 Reaction Stoichiometry
    5. 4.4 Reaction Yields
    6. 4.5 Quantitative Chemical Analysis
    7. Key Terms
    8. Key Equations
    9. Summary
    10. Exercises
  6. 5 Thermochemistry
    1. Introduction
    2. 5.1 Energy Basics
    3. 5.2 Calorimetry
    4. 5.3 Enthalpy
    5. Key Terms
    6. Key Equations
    7. Summary
    8. Exercises
  7. 6 Electronic Structure and Periodic Properties of Elements
    1. Introduction
    2. 6.1 Electromagnetic Energy
    3. 6.2 The Bohr Model
    4. 6.3 Development of Quantum Theory
    5. 6.4 Electronic Structure of Atoms (Electron Configurations)
    6. 6.5 Periodic Variations in Element Properties
    7. Key Terms
    8. Key Equations
    9. Summary
    10. Exercises
  8. 7 Chemical Bonding and Molecular Geometry
    1. Introduction
    2. 7.1 Ionic Bonding
    3. 7.2 Covalent Bonding
    4. 7.3 Lewis Symbols and Structures
    5. 7.4 Formal Charges and Resonance
    6. 7.5 Strengths of Ionic and Covalent Bonds
    7. 7.6 Molecular Structure and Polarity
    8. Key Terms
    9. Key Equations
    10. Summary
    11. Exercises
  9. 8 Advanced Theories of Covalent Bonding
    1. Introduction
    2. 8.1 Valence Bond Theory
    3. 8.2 Hybrid Atomic Orbitals
    4. 8.3 Multiple Bonds
    5. 8.4 Molecular Orbital Theory
    6. Key Terms
    7. Key Equations
    8. Summary
    9. Exercises
  10. 9 Gases
    1. Introduction
    2. 9.1 Gas Pressure
    3. 9.2 Relating Pressure, Volume, Amount, and Temperature: The Ideal Gas Law
    4. 9.3 Stoichiometry of Gaseous Substances, Mixtures, and Reactions
    5. 9.4 Effusion and Diffusion of Gases
    6. 9.5 The Kinetic-Molecular Theory
    7. 9.6 Non-Ideal Gas Behavior
    8. Key Terms
    9. Key Equations
    10. Summary
    11. Exercises
  11. 10 Liquids and Solids
    1. Introduction
    2. 10.1 Intermolecular Forces
    3. 10.2 Properties of Liquids
    4. 10.3 Phase Transitions
    5. 10.4 Phase Diagrams
    6. 10.5 The Solid State of Matter
    7. 10.6 Lattice Structures in Crystalline Solids
    8. Key Terms
    9. Key Equations
    10. Summary
    11. Exercises
  12. 11 Solutions and Colloids
    1. Introduction
    2. 11.1 The Dissolution Process
    3. 11.2 Electrolytes
    4. 11.3 Solubility
    5. 11.4 Colligative Properties
    6. 11.5 Colloids
    7. Key Terms
    8. Key Equations
    9. Summary
    10. Exercises
  13. 12 Kinetics
    1. Introduction
    2. 12.1 Chemical Reaction Rates
    3. 12.2 Factors Affecting Reaction Rates
    4. 12.3 Rate Laws
    5. 12.4 Integrated Rate Laws
    6. 12.5 Collision Theory
    7. 12.6 Reaction Mechanisms
    8. 12.7 Catalysis
    9. Key Terms
    10. Key Equations
    11. Summary
    12. Exercises
  14. 13 Fundamental Equilibrium Concepts
    1. Introduction
    2. 13.1 Chemical Equilibria
    3. 13.2 Equilibrium Constants
    4. 13.3 Shifting Equilibria: Le Châtelier’s Principle
    5. 13.4 Equilibrium Calculations
    6. Key Terms
    7. Key Equations
    8. Summary
    9. Exercises
  15. 14 Acid-Base Equilibria
    1. Introduction
    2. 14.1 Brønsted-Lowry Acids and Bases
    3. 14.2 pH and pOH
    4. 14.3 Relative Strengths of Acids and Bases
    5. 14.4 Hydrolysis of Salt Solutions
    6. 14.5 Polyprotic Acids
    7. 14.6 Buffers
    8. 14.7 Acid-Base Titrations
    9. Key Terms
    10. Key Equations
    11. Summary
    12. Exercises
  16. 15 Equilibria of Other Reaction Classes
    1. Introduction
    2. 15.1 Precipitation and Dissolution
    3. 15.2 Lewis Acids and Bases
    4. 15.3 Multiple Equilibria
    5. Key Terms
    6. Key Equations
    7. Summary
    8. Exercises
  17. 16 Thermodynamics
    1. Introduction
    2. 16.1 Spontaneity
    3. 16.2 Entropy
    4. 16.3 The Second and Third Laws of Thermodynamics
    5. 16.4 Free Energy
    6. Key Terms
    7. Key Equations
    8. Summary
    9. Exercises
  18. 17 Electrochemistry
    1. Introduction
    2. 17.1 Balancing Oxidation-Reduction Reactions
    3. 17.2 Galvanic Cells
    4. 17.3 Standard Reduction Potentials
    5. 17.4 The Nernst Equation
    6. 17.5 Batteries and Fuel Cells
    7. 17.6 Corrosion
    8. 17.7 Electrolysis
    9. Key Terms
    10. Key Equations
    11. Summary
    12. Exercises
  19. 18 Representative Metals, Metalloids, and Nonmetals
    1. Introduction
    2. 18.1 Periodicity
    3. 18.2 Occurrence and Preparation of the Representative Metals
    4. 18.3 Structure and General Properties of the Metalloids
    5. 18.4 Structure and General Properties of the Nonmetals
    6. 18.5 Occurrence, Preparation, and Compounds of Hydrogen
    7. 18.6 Occurrence, Preparation, and Properties of Carbonates
    8. 18.7 Occurrence, Preparation, and Properties of Nitrogen
    9. 18.8 Occurrence, Preparation, and Properties of Phosphorus
    10. 18.9 Occurrence, Preparation, and Compounds of Oxygen
    11. 18.10 Occurrence, Preparation, and Properties of Sulfur
    12. 18.11 Occurrence, Preparation, and Properties of Halogens
    13. 18.12 Occurrence, Preparation, and Properties of the Noble Gases
    14. Key Terms
    15. Summary
    16. Exercises
  20. 19 Transition Metals and Coordination Chemistry
    1. Introduction
    2. 19.1 Occurrence, Preparation, and Properties of Transition Metals and Their Compounds
    3. 19.2 Coordination Chemistry of Transition Metals
    4. 19.3 Spectroscopic and Magnetic Properties of Coordination Compounds
    5. Key Terms
    6. Summary
    7. Exercises
  21. 20 Organic Chemistry
    1. Introduction
    2. 20.1 Hydrocarbons
    3. 20.2 Alcohols and Ethers
    4. 20.3 Aldehydes, Ketones, Carboxylic Acids, and Esters
    5. 20.4 Amines and Amides
    6. Key Terms
    7. Summary
    8. Exercises
  22. 21 Nuclear Chemistry
    1. Introduction
    2. 21.1 Nuclear Structure and Stability
    3. 21.2 Nuclear Equations
    4. 21.3 Radioactive Decay
    5. 21.4 Transmutation and Nuclear Energy
    6. 21.5 Uses of Radioisotopes
    7. 21.6 Biological Effects of Radiation
    8. Key Terms
    9. Key Equations
    10. Summary
    11. Exercises
  23. A | The Periodic Table
  24. B | Essential Mathematics
  25. C | Units and Conversion Factors
  26. D | Fundamental Physical Constants
  27. E | Water Properties
  28. F | Composition of Commercial Acids and Bases
  29. G | Standard Thermodynamic Properties for Selected Substances
  30. H | Ionization Constants of Weak Acids
  31. I | Ionization Constants of Weak Bases
  32. J | Solubility Products
  33. K | Formation Constants for Complex Ions
  34. L | Standard Electrode (Half-Cell) Potentials
  35. M | Half-Lives for Several Radioactive Isotopes
  36. Answer Key
    1. Chapter 1
    2. Chapter 2
    3. Chapter 3
    4. Chapter 4
    5. Chapter 5
    6. Chapter 6
    7. Chapter 7
    8. Chapter 8
    9. Chapter 9
    10. Chapter 10
    11. Chapter 11
    12. Chapter 12
    13. Chapter 13
    14. Chapter 14
    15. Chapter 15
    16. Chapter 16
    17. Chapter 17
    18. Chapter 18
    19. Chapter 19
    20. Chapter 20
    21. Chapter 21
  37. Index

15.1 Precipitation and Dissolution

The equilibrium constant for an equilibrium involving the precipitation or dissolution of a slightly soluble ionic solid is called the solubility product, Ksp, of the solid. When we have a heterogeneous equilibrium involving the slightly soluble solid MpXq and its ions Mm+ and Xn–:

MpXq(s)pMm+(aq)+qXn−(aq)MpXq(s)pMm+(aq)+qXn−(aq)

We write the solubility product expression as:

Ksp=[Mm+]p[Xn−]qKsp=[Mm+]p[Xn−]q

The solubility product of a slightly soluble electrolyte can be calculated from its solubility; conversely, its solubility can be calculated from its Ksp, provided the only significant reaction that occurs when the solid dissolves is the formation of its ions.

A slightly soluble electrolyte begins to precipitate when the magnitude of the reaction quotient for the dissolution reaction exceeds the magnitude of the solubility product. Precipitation continues until the reaction quotient equals the solubility product.

A reagent can be added to a solution of ions to allow one ion to selectively precipitate out of solution. The common ion effect can also play a role in precipitation reactions. In the presence of an ion in common with one of the ions in the solution, Le Châtelier’s principle applies and more precipitate comes out of solution so that the molar solubility is reduced.

15.2 Lewis Acids and Bases

G.N. Lewis proposed a definition for acids and bases that relies on an atom’s or molecule’s ability to accept or donate electron pairs. A Lewis acid is a species that can accept an electron pair, whereas a Lewis base has an electron pair available for donation to a Lewis acid. Complex ions are examples of Lewis acid-base adducts. In a complex ion, we have a central atom, often consisting of a transition metal cation, which acts as a Lewis acid, and several neutral molecules or ions surrounding them called ligands that act as Lewis bases. Complex ions form by sharing electron pairs to form coordinate covalent bonds. The equilibrium reaction that occurs when forming a complex ion has an equilibrium constant associated with it called a formation constant, Kf. This is often referred to as a stability constant, as it represents the stability of the complex ion. Formation of complex ions in solution can have a profound effect on the solubility of a transition metal compound.

15.3 Multiple Equilibria

Several systems we encounter consist of multiple equilibria, systems where two or more equilibria processes are occurring simultaneously. Some common examples include acid rain, fluoridation, and dissolution of carbon dioxide in sea water. When looking at these systems, we need to consider each equilibrium separately and then combine the individual equilibrium constants into one solubility product or reaction quotient expression using the tools from the first equilibrium chapter. Le Châtelier’s principle also must be considered, as each reaction in a multiple equilibria system will shift toward reactants or products based on what is added to the initial reaction and how it affects each subsequent equilibrium reaction.

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