Key Terms
- equilibrium
- state of a reversible reaction in which the forward and reverse processes occur at equal rates
- equilibrium constant (K)
- value of the reaction quotient for a system at equilibrium; may be expressed using concentrations (Kc) or partial pressures (Kp)
- heterogeneous equilibria
- equilibria in which reactants and products occupy two or more different phases
- homogeneous equilibria
- equilibria in which all reactants and products occupy the same phase
- law of mass action
- when a reversible reaction has attained equilibrium at a given temperature, the reaction quotient remains constant
- Le Châtelier’s principle
- an equilibrium subjected to stress will shift in a way to counter the stress and re-establish equilibrium
- reaction quotient (Q)
- mathematical function describing the relative amounts of reactants and products in a reaction mixture; may be expressed in terms of concentrations (Qc) or pressures (Qp)
- reversible reaction
- chemical reaction that can proceed in both the forward and reverse directions under given conditions