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activation energy
energy necessary for reactions to occur
active site
specific region of the enzyme to which the substrate binds
allosteric inhibition
inhibition by a binding event at a site different from the active site, which induces a conformational change and reduces the affinity of the enzyme for its substrate
(also, anabolism) pathways that require an input of energy to synthesize complex molecules from simpler ones
adenosine triphosphate, the cell’s energy currency
study of energy flowing through living systems
(also, catabolism) pathways in which complex molecules are broken down into simpler ones
chemical energy
potential energy in chemical bonds that is released when those bonds are broken
small organic molecule, such as a vitamin or its derivative, which is required to enhance the activity of an enzyme
inorganic ion, such as iron and magnesium ions, required for optimal regulation of enzyme activity
competitive inhibition
type of inhibition in which the inhibitor competes with the substrate molecule by binding to the active site of the enzyme
process that changes the natural properties of a substance
describes chemical reactions that require energy input
energy coupling
process during which energy released by one reaction is used to drive another reaction
total energy of a system
entropy (S)
measure of randomness or disorder within a system
describes chemical reactions that release free energy
feedback inhibition
effect of a product of a reaction sequence to decrease its further production by inhibiting the activity of the first enzyme in the pathway that produces it
free energy
Gibbs free energy is the usable energy, or energy that is available to do work.
energy energy transferred from one system to another that is not work (energy of the motion of molecules or particles)
heat energy
total bond energy of reactants or products in a chemical reaction
induced fit
dynamic fit between the enzyme and its substrate, in which both components modify their structures to allow for ideal binding
kinetic energy
type of energy associated with objects or particles in motion
all the chemical reactions that take place inside cells, including anabolism and catabolism
phosphoanhydride bond
bond that connects phosphates in an ATP molecule
potential energy
type of energy that has the potential to do work; stored energy
molecule on which the enzyme acts
study of energy and energy transfer involving physical matter
transition state
high-energy, unstable state (an intermediate form between the substrate and the product) occurring during a chemical reaction
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